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Primal Fire is a molten chunk of pure fire goodness. It is used in a wide range of high-end recipes.
Source
Primal fire can be created through Alchemy with the Transmute: Primal Air to Fire and 
[Transmute: Primal Mana to Fire] recipes. It can also be created by turning 10 Motes of Fire into one Primal Fire, similar to Enchanting Essences.
Primal Fire as an Ingredient
Primal Fire is used in the following recipes:
Alchemy
[Major Fire Protection Potion]- [Transmute: Primal Fire to Earth]
- [Transmute: Primal Fire to Mana]
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Blacksmithing
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- [Felsteel Shield Spike]
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[Ragesteel Breastplate]
[Ragesteel Gloves]- [Ragesteel Helm]
- [Red Belt of Battle]
- [Red Havoc Boots]
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Engineering
- [Dimensional Ripper - Area 52]
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- [Gnomish Battle Goggles]
- [Gnomish Flame Turret]
- [Gnomish Power Goggles]
- [Goblin Rocket Launcher]
- [Khorium Power Core]
Jewelcrafting
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- [Figurine - Living Ruby Serpent]
- [Khorium Inferno Band]
- [Pendant of Frozen Flame]
- [Pendant of Thawing]
Leatherworking
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- [Drums of War]
- [Ebon Netherscale Belt]
- [Ebon Netherscale Bracers]
- [Ebon Netherscale Breastplate]
- [Frost Armor Kit]
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- [Stylin' Crimson Hat]
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Tailoring
- [Belt of Blasting]
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- [Netherflame Belt]
- [Netherflame Boots]
- [Netherflame Robe]
- [Spellfire Belt]
- [Spellfire Gloves]
- Spellfire Vest
